Product ID:SYNASOL SOLVENT,PM-3224,190 PROOF
MSDS Date:06/11/1992
FSC:6850
NIIN:00-188-9875
MSDS Number: BQQDP

UNION CARBIDE CORP., LINDE DIV.

39 OLD RIDGEBURY RD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357/304-744-3487

Info Phone: 304-744-3487

Cage: 36346

UNION CARBIDE CORP LINDE DIV

DANBURY, CT 06817-0001 US

Telephone: 800-822-4357; 304-744-3487

Cage: 36346

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 85.4%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9293

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 7.0%

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 3.6%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ACETATE (SARA III)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 1.3%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ALIPHATIC HYDROCARBON

Fraction By Weight: 0.8%

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 1.9%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:TLV FOR ETHYL ALCOHOL IS 1000 PPM.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALE:EXPOSURE TO OVER 1000 PPM
MAY CAUSE HEADACHE,DROWSINESS,LASSITUDE,LOSS OF APPETITE,LACK OF
CONCENTRATION,IRRITATION OF THROAT.ORAL:CAN CAUSE CNS
DEPRESSION,NAUSEA,VOMITING,DIARRHEA,FETAL ALCOHOL SYNDROME IN
OFFSPRING.EYES:IRRITATION.SKIN:DEFATTING.CHRONIC-DRYNESS OF
SKIN,DERMATITIS & ALCOHOLISM.
Effects of Overexposure:EXPOSURE TO OVER 1000 PPM MAY CAUSE HEADACHE,
DROWSINESS, LASSITUDE, LOSS OF APPETITE, LACK OF CONCENTRATION,
IRRITATION OF THROAT. ORALLY CAN CAUSE CNS DEPRESSION, NAUSEA,
VOMITING, DIARRHEA. EYE IRR ITATION. SKIN DEFATTING. CAN BE
ABSORBEDTHROUGH DAMAGED SKIN.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:I F CONSCIOUS, DRINK 2 GLASSES OF WATER &INDUCE VOMITING. CALL
A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY.

Flash Point Method:TCC
Flash Point:57.0F,13.9C
Lower Limits:3.3 (ETOH)
Upper Limits:19 (ETOH)
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. WATER
MAY BE INEFFECTIVE, BUT SHOULD BE USED TO COOL FIRE-EXPOSED
CONTAINERS
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. STOP LEAK IF POSSIBLE. SMALL SPILLS
CAN BE FLUSHED WITH LARGE AMOUNT OF WATER. LARGE SPILLS SHOULD BE
COLLECTED FOR DISPOSAL.

Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES, IN WELL
VENTILATED AREA AWAY FROM SOURCES OF IGNITION AND INCOMPATIBLE
MATERIALS.
Other Precautions:USE WITH ADEQUATE VENTILATION. AVOID EYE OR SKIN
CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. KEEP OUT OF
REACH OF CHILDREN. POISON. CONTAINS METHANOL. DO NOT TAKE
INTERNALLY. FOR INDUSTRIAL US E ONLY.

Respiratory Protection:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IN HIGH VAPOR CONCENTRATIONS.
Ventilation:GENERAL VENTILATION ACCEPTABLE. USE LOCAL EXHAUST
(EXPLOSION PROOF) AT POINTS WHERE VAPORS CAN ESCAPE TO WORKPLACE
AIR.
Protective Gloves:NEOPRENE
Eye Protection:SAFETY GLASSES OR MONOGOGGLES
Other Protective Equipment:WEAR PROTECTIVE CLOTHING IN CASE OF REPEATED
OR PROLONGED CONTACT. PROVIDE EYE WASH & SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE &
LAUNDER CONTAMINATED CLOTHING.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A UNDER THE SAME
NSN. NOTE TO PHYSICIAN:GASTRIC LAVAGE USING INTUBATION IS
RECOMMENDED. AVOID DEPRESSANT DRUGS OR EXCESSIVE FLUID. NALOXONE
(0.4-1.2 MG IV) MAY AROUSE ETHANOL-INTOXICATED PATIENTS.
HEMODIALYSIS IS INDICATED IF BLODD ETHANOL LEVEL IS ABOVE 5 MG/ML.

HCC:F2
Boiling Pt:B.P. Text:171F,77C
Melt/Freeze Pt:M.P/F.P Text:<-130F,<-90
Vapor Pres:48.4 @ 20C
Vapor Density:1.6
Spec Gravity:0.79
Evaporation Rate & Reference:3.6 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT AND COLORLESS LIQUID - CHARACTERISTIC
ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG INORGANIC ACIDS
Stability Condition to Avoid:HEAT, SPARKS, FLAME, STATIC ELECTRICITY,
HOT SURFACES
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE

Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.